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Specific Intermolecular Interactions of Element-Organic Compounds

  • Book
  • © 2015

Overview

Authors:
  1. Alexei K. Baev

    1. G.A.Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

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  • Describes the development of the thermodynamic theory of specific intermolecular interactions
  • Describes a wide spectrum of types of intermolecular interactions
  • The topic is relevant to organic, organometallic and synthetic chemistry
  • Includes supplementary material: sn.pub/extras

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Table of contents (5 chapters)

  1. Front Matter

    Pages i-xxiv
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  2. Hydrogen Bonds of Hydrides and Specific Interactions of Alkyl Compounds of Main Group Elements

    • Alexei K. Baev
    Pages 1-48

  3. Specific Intermolecular Interactions of Silanes and Their Derivatives

    • Alexei K. Baev
    Pages 49-118

  4. Specific Interactions of Elementorganic Compounds of Germanium Subgroup Elements

    • Alexei K. Baev
    Pages 119-141

  5. Specific Intermolecular Interactions of Sulfonated Organic Compounds

    • Alexei K. Baev
    Pages 143-215

  6. Specific Intermolecular Interactions of Sulfur, Oxygen, and Nitrogenated Organic Compounds

    • Alexei K. Baev
    Pages 217-273

  7. Back Matter

    Pages 275-278
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Keywords

About this book

This book extends the development of the thermodynamic theory of specific intermolecular interactions to element-organic and specific organometallic compounds. The fundamentals of an unconventional approach to the theory of H-bonding and specific interactions are formulated, based on a concept of pentacoordinate carbon atoms. Prof. Baev has introduced the theory already in his successful books "Specific Intermolecular Interactions of Organic Compounds" and "Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds". In this book he also demonstrates it for element organic and specific organometallic compounds, a class of substances which is of great importance in synthetic chemistry and catalysis. Furthermore, organic compound classes, that have not been treated in the previous books, are included. New types of hydrogen bonds and specific interactions are substantiated and their energies are determined on the basis of the developed methodology. In this way, the influence of the molecular structure on the energy and on intermolecular interactions can be discussed for these particular compound classes.

Authors and Affiliations

  • G.A.Krestov Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    Alexei K. Baev

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